Qualified is important, and that means proper training - same as the Utility forestry department gets (that is where I started my work - and I was trained by the Utility forestry training units - and worked there for the beginning of my career)
But as mentioned you also need the proper authorization/permission, best to have the Utility company on site when you do it.
And depending upon size of tree limbs and proximity to the lines you may need to have special equipment (which most of us do not have). Certainally always ensure you have proper equipment before you begin (this may include insulated gloves, insulated boom on truck, etc).
Some tree species are better conductors than others, and at higher voltages you do not want to play around - better to ask the questions and be safe first then have somebody else worry about it later (because you may not be there to worry!).