Just my opinion here, but a 66 has always been just a plain cold blooded saw to get started, it is one of the worst when it comes to starting one of Sthil's modern day saws, in talking to some of the local tree services and one logger all say the same thing. It also seems to be prone to flooding. Another trick I have had luck with is to set the choke between open (run)and the factory setting of a half choke, there is no setting there it is something you have to feel for to get it work and start.
I haven't done any changes to our 66 since the day one, it is still a stock saw, that is going to change one of these years. I have gotten better results starting by turning the low speed screw all the way in, with the limiter caps on the carb I'm sure it is pushed to the limit for a lean running condition, it hasn't blown up yet and has been set this way for over a year, if it does go over the edge it will give me a good excuse to rebuild it.
Sthil 066 also seems to be touchy to start becuse of a dirty air filter compared to other saws. I have to keep after this one more so than other saws.
Other than these little Mickey Mouse problems, a 66 is a good running, cutting saw after it gets warmed up, you can't go to step two without going through step one.
Larry