Ahh, the trials and tribulations of square filing. That is what it is all about. I have ruined many a chains trying to get the angle just right. It is very hard when first learning to keep the file at the same angle on all the teeth. It is then hard to transfer those angles to the other side. Remeber, you are trying to keep four angles with one swipe of the file. Study that new square ground chain very well. Here is a link to madsens to help with the angles. More hook cuts mush faster, but doesn't stay sharp all that long
http://www.madsens1.com/angles.htm
When you file, you are going from the outside of the cutter, to the inside. It is opposite of the round filing you are probably used to.
With the double bevel file, you want it at roughly 45 degrees, and the top point of the angle will be on line with the working corner.
Try practicing on used chains first. Just make sure the chains are clean. I use a pressure washer to get all the sap and gunk off of them before starting. The files don't like any crap on the chain. Try to keep the chain extremely tight if you are trying to sharpen it on the bar. If it is loose and it chatters, it will destroy the edge of the file that you are trying to create the working corner. Also, try not to run the file backwards. That seems like stupid information, but I buggered up a file or two by doing that. I was trying to keep the "line" by not removing the file completely from the tooth.
Also, try to get as much light as you can on the corner of the tooth.
The rest is just practice. I can make the teeth look great, but the consistancy is the key. I am still havin a little trouble with that. Good luck, and if you want to stop by, let me know. I might be able to show you a thing or two. I also have a couple of the triangluar files, if you want to try one of those, although I haven't quite figured those out yet.
-Steve