When we've done any stump spraying, if its in a residential area, we use Tordon RTU. its blue in color and comes in quart bottles. easy to use and relatively inexpensive ($13/qt).
As for large scale stump spraying, we use either garlon or remedy. I think its about 3oz per gallon of Diesel. The diesel helps hold the chemical on the stump, acts as a sticker. Saturate the whole stump. I believe it can be applied to dry stumps (non-fresh cut). Sure it may be pricey, but the cost can be passed on to the customer. It sure works though.
with the tordon, the cuts have to be close to ground level and fresh.
Just remember, if there are any trees staying of like specie that are in close proximity to the ones being removed, you run the risk of killing them through grafted roots. Make sure your customer knows this and give it to him/her in writing with your disclaimer. It could keep you out of court or having to do more work for free.
As for round up, it doesnt work on stumps well. Maybe small volunteers in a cedar hedge, but not large ones.
One other that comes to mind, SPIKE. THIS IS EXTREMELY DANGEROUS TO OTHER PLANTS. It travels far and wide. I would not recommend this, just thought id let you know its there too.