I was thinking of putting all 250 feet in a 5 gal pail of alcohol, let it
soak for an afternoon then put it in an onion bag and give it a run
through a big washing machine to make sure all the dirt and grit
gets washed out. I'd figure that the pail should be good for a few
soakings so just put a lid on it and keep it aside.
Does the onion bag sound crazy or could it be a good idea for washing
ropes in the washing machine?
-Jason
Let's do some simple math. 250 feet of 1/2 in rope has a volume of roughly 2 gallons. Once you stuff it in the bucket, you have room for about 3 gallons of alcohol. Leave enough room to move stuff around, and you have 2 gallons of alcohol and 2 gallons of rope. Let's say the rope has space between the fibers amounting to, say, 20% of its volume (this would be a lot less if the rope were under tension). So 0.4 gallons space in the rope. Of the 2 gallons of alcohol, .4 gallons ends up in the rope, or 20%. Since the pitch all ends up dissolved in the alcohol, 20% of the pitch remains in the rope, and 80% ends up in the bucket.
If on some subsequent day you decide to wash the rope again, in the same alcohol, but the rope is only 1/5 as dirty as the first time, the acohol won't clean it at all because it is exactly as dirty as the rope.
What's more, if you immerse the rope in alcohol, whether for the 1st time or the nth time, perfectly clean sections of rope will become impregnated with pitch.
The method I described earlier using a small (3" X 3") rag, is probably a little better. It won't sully clean sections of rope. You can throw away the rag when it gets dirty and pick up another one. You can get by with very little alcohol (I have used less than 3 quarts in 2 years, and I clean my rope and split tail almost every time I climb). But this method also will leave some pitch in the rope.
What happens to the pitch left in the rope? Since it was dissolved in the alcohol, and is left behind when the alcohol evaporates, it is distributed through the rope in a very thin film, probably only a few molecules thick. In this condition is would be very prone to oxidation because it would have an enormous surface area and because it (mostly various forms of terpenes) is full of double bonds, which are easy for oxygen to attack. The products of oxidation would almost certainly be various aldehydes, ketones, alcohols, and carboxylic acids, none of which should harm the rope, none of which should be tacky, and many of which would probably evaporate away or fall away as harmless powder. My guess is that this acceleration of oxidative degradation, rather than actual cleaning of the rope, is the major effect of cleaning the rope with alcohol or acetone.