I did some testing one day using every solvent in my shop... I used Simple Green, mineral spirits, rubbing alcohol, lacquer thinner, acetone, carb cleaner, brake cleaner, gasoline, WD-40, Marvel Mystery Oil, Goo Gone, K2R, Coleman Fuel, and denatured alcohol. By far the denatured alcohol did the best job on tree sap.
I buy denatured alcohol at home improvement/hardware stores by the gallon for use with shellac and for cleaning surfaces in my shop. You can also get it as stove fuel in boating and outdoors stores--read the labels as white gas/Coleman Fuel are sold as stove fuel also!
It doesn't damage paint on automobiles. I get to do that chore Friday now that the weather has turned. This as there is a large white pine next to my lady friend's driveway that leaves big globs on the cars. I found that the sap remover from the auto parts stores is a lot more expensive and doesn't work nearly as well...
I use it to get sap off myself and clothing too... It does dry your skin out but before I retired that was better than having black spots all over my hands for a week!