Volume of a cone = 1/12 x 3.14 x height x square of diameter of base.If you slap this into google, "volume of cone" , the top link right directly on the page is an online calculator for volume of a cone. As to how much to subtract for air space, dang not sure, 15%-20% maybe? I'm guessing there.
Suppose the height of the wood pile is 8' and its diameter is 20'. The volume of the wood pile is approximated as (1/12)(3.14)(8)(20)(20) = 837 cu ft.
The amount of equivalent cords of stacked wood in that pile will vary from this amount based on average log length and average diameter. You might have 5 cords there, but you will not have 6.5. The actual amount will depend on who bucked the logs and who split the rounds.
It will also vary based on who measured the pile of logs and how many beers he drank before he measured it.