I use vinegar as my acid remover. I will eat thru some chrome plating if you let it soak for too long. Then when I'm done I just pour it in my drive way to kill the grass. Get 2 for 1 use out of it.
I use vinegar as my acid remover. I will eat thru some chrome plating if you let it soak for too long.
Oxalic acid is an organic compound with the formula H2C2O4. It is a colorless crystalline solid that dissolves in water to give colorless solutions. It is classified as a dicarboxylic acid. In terms of acid strength, it is much stronger than acetic acid. Oxalic acid is a reducing agent and its conjugate base, known as oxalate, is a chelating agent for metal cations. Typically, oxalic acid occurs as the dihydrate.
Oral consumption of oxalic acid or prolonged skin contact is dangerous.
Oxalic acid's main applications include cleaning or bleaching, especially for the removal of rust (iron complexing agent), e.g. Bar Keepers Friend is an example of a household cleaner containing oxalic acid. Its utility in rust removal agents is due to its forming a stable, water soluble salt with ferric iron, ferrioxalate ion.
Looked all over for the stuff: area hardware/home center/farm stores, etc. Found that not all 'wood bleach' is OA. Some had other stuff in it or hydrogen peroxide.
Called a friend who is a high school science teacher, but his sources were expensive.
Found some on eBay for a reasonable price ($25 for 5 pounds), but that sounds like a lot of OA, and buying chemicals over eBay made me a little uncomfortable.
Found it on Amazon! Lots of sizes. Good prices. Free shipping. Ordered 2 pounds for $9 shipped. Will post my results in 'Philbert's Chain Salvage Challenge' thread.
One Internet post cautioned about leaving parts in too long - said it left a 'hard to remove' scale coating behind.
Philbert
Can't find your challenge thread. Remember seeing it in the index earlier. Did a google search for it and found the link............but I get an error message when I try to open it. Strange....
The Site is somewhat erratic right now. Hope it settles out soon.
Got 2 pounds of the stuff in the mail, and at 3 ounces (liquid measure = 6 Table spoons = 1.5 coffee scoops) per gallon it is actually cheaper than vinegar at the grocery store.
Working on a challenge chain right now with it and, so far, am impressed. More so than the EvapoRust stuff.
Will post my results in that other thread to keep things organized.
Philbert
Hey Phil need a link that works
LikeHaven't been posting photos due to the site issues, and my main computer going in for repair, but wanted to report some positive results with a frozen chain that someone gave me as a test challenge.
.404 loop reportedly left hanging on a nail in a shed. Color was a battleship grey - almost looked like someone had sprayed automotive primer evenly across it. Not all of the links were seized, but if you held it up in the air it remained a full circle, and trying to move some links just to get it to fit into a pan for soaking took some effort.
3+ days in a 3oz OA/gallon of water solution and 90% of the links now move freely! This was not a dip-and-clean solution. I changed the solution whenever it got heavily clouded, aggressively brushed down the links with a stainless steel 'scratch brush' (welding item - like an oversized toothbrush) between baths, and worked the links (some with a couple pair of pliers). A lot of work involved.
Looks like a chain now. Can read the markings. Going to give it another day or two to see if I can get all of the rivets loose using just OA, and not going to the acetone/ATF solution mentioned in other threads.
Of course, rust eats metal. And just because I can remove the rust and free the links does not mean that the rivets won't snap when the chain is run. But I am feeling positive about this one.
Philbert
I bought two pounds shipped from an Amazon seller. My rototiller wouldn't start when I went to put it away for winter. It sat out during the flood and I noticed that the air filter housing was rusted on the inside. Also the recoil was busted and the carb isn't pumping fuel. I have to stop loaning tools out.
For $9 the oxalic acid is worth a shot. Thanks to the OP for starting this thread.
The oxyalic acid worked so so on the rusted tiller parts. It left some staining on the metal, but removed all the crusty rusty. I'm not sure it was worth the effort of buying the acid, mixing it and disposing of it.