Work hardening,is when the metal is subject to excessive[above the critical temp],and undergoes a molecular change in it's structure.Case in point.Take a piece of A2[air hardening tool steel],chuck it in a lathe,and take successive,shallow cuts,that don' t roll a good chip.In short order,you won't be able to cut it anymore.It will get so hard,that carbide tooling will glow red.This phenomenon,can occur on any steel,that contains enough carbon,to be hardened.It not an altogether bad thing.Those that are old enough to remember when the tetra ethyl lead,was removed from the gasoline,can recall some of the concerns.The lead was one of the lubricants of the exhaust valves.The worry was,that the valves would seize due to lack of this compound.As it turned out,most of the engines had work,or wear,if you will,hardened valves,guides etc.due to running for years,and very few engines suffered.There were,of course,exceptions to that.