Johny Utah
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When used as an antiknock agent, alcohol will cause fuel to absorb moisture from the air. Over time fuel humidity can rise leading to rusting and corrosion in the fuel line. Whereas TEL is highly soluble in gasoline, ethanol is poorly soluble and that solubility decreases as fuel humidity increases. Over time, droplets and pools of water can form in the fuel system creating a risk for fuel line icing. High fuel humidity can also raise issues of biological contamination, as certain bacteria can grow on the surface of the water/gasoline interface thus forming bacterial mats in the fuel system. TEL's biocidal properties helped prevent fuel contamination and degradation from bacterial growth.
In most Western countries this additive went out of use in the late 20th century because of the concerns over pollution of air and soil (e.g., the areas around roads) and the accumulative neurotoxicity of lead. The use of TEL as a fuel additive spoils catalytic converters, which became mandatory to meet emissions regulations from the 1970s on in the West. The need for TEL was lessened by several advances in automotive engineering and petroleum chemistry. Lower oil prices promoted the development of low compression engines that were not as sensitive to gasoline quality. Other antiknock additives of various toxicities (MMT, MTBE, ETBE) and safer methods for making higher octane blending stocks (reformate, iso-octane) reduced the need for TEL.
In most Western countries this additive went out of use in the late 20th century because of the concerns over pollution of air and soil (e.g., the areas around roads) and the accumulative neurotoxicity of lead. The use of TEL as a fuel additive spoils catalytic converters, which became mandatory to meet emissions regulations from the 1970s on in the West. The need for TEL was lessened by several advances in automotive engineering and petroleum chemistry. Lower oil prices promoted the development of low compression engines that were not as sensitive to gasoline quality. Other antiknock additives of various toxicities (MMT, MTBE, ETBE) and safer methods for making higher octane blending stocks (reformate, iso-octane) reduced the need for TEL.
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