I think the canned fuel is higher octane for longer shelf life. Fuel octane degrades over time, so if you start off with 87, open the can and it sits several months or a year you could be in the low 80's by the time you get around to using it. Starting with 93, hopefully it won't degrade to the point of predetonation before it gets used up. Just my thoughts.
In the central southern US where I live/travel, ethanol is in all grades of gasoline. If you do find a place that has some ethanol-free fuel, it will likely be 87 or 89 octane. There is 1 store in my town that only sells ethanol-free gasoline, and in all grades. Very well may be different in different areas - this is just what I have seen local to me.
Waylan