Mixed 100LL is far less expensive than the canned fuels.
100LL was recommended as fuel in the old Chevrolet Hi-Perf Manual (Chevy Power). It had all the high performance parts/part numbers listed by engine type (big block, small block, cosworth DOC 4....)
I still run it in my 68 Camaro. It has an 11:1 69 LT1 motor that has been decked and heads surfaced, compression is somewhere about 11.5-12:1. I can get by with cutting it 50:50 with pump premium.
Years ago I could pull right up to the pumps at the airport and do a burnout on the tarmack. The kid pumping gas was happy to see me. 9/11 put an end to that.
Every small airport around me will sell 100LL. There was one that used to have the green 130 octane fuel.